Broadband and Wide Angle Nonreciprocal Thermal Emission from Weyl Semimetal Structures

Nonreciprocal thermal emission is a cutting-edge technology that enables fundamental control over thermal radiation and has exciting applications in thermal energy harvesting. However, so far one of the foremost challenges is making nonreciprocal emission to operate over a broad wavelength range and for multiple angles. In this work, we solve this outstanding problem by proposing three different types of structures always utilizing only one Weyl semimetal (WSM) thin film combined with one or two additional dielectric or metallic layers and terminated by a metallic substrate. First a tradeoff relationship between the magnitude and bandwidth of the thermal nonreciprocity contrast is established based on the thickness of the WSM film. Then, the bandwidth broadening effect is demonstrated via the insertion of a dielectric spacer layer that can also be fine-tuned by varying its thickness. Finally, further control on the resulting strong nonreciprocal thermal radiation is demonstrated by the addition of a thin metallic layer in the proposed few layer designs. The presented composite structures work for a broad frequency range and multiple emission angles, consisting highly advantageous properties to various nonreciprocal thermal radiation applications. Moreover, the proposed designs do not require any patterning and can be experimentally realized by simple deposition fabrication methods. They are expected to aid in the creation of broadband nonreciprocal thermal emitters that can find applications in new energy harvesting devices

Quantitative P-31 NMR Analysis of Lignins and Tannins

The development of sustainable biorefinery products is confronted, among others, with the challenge of lignin and tannin valorization. These abundant, renewable aromatic biopolymers have not been widely exploited due to their inherent structural complexity and high degrees of variability and species diversity. The lack of a defined primary structure for these polyphenols is further compounded with complex chemical alterations induced during processing, eventually imparting a large variety of structural features of extreme significance for any further utilization efforts.Consequently, a protocol for the rapid, simple, and unequivocal identification and quantification of the various functional groups present in natural polyphenols, is a fundamental prerequisite for understanding and accordingly tailor their reactivity and eventual utility.Quantitative P-31 NMR offers the opportunity to rapidly and reliably identify unsubstituted, o-mono substituted, and o-disubstituted phenols, aliphatic OHs, and carboxylic acid moieties in lignins and tannins with broad application potential.The methodology consists of an in situ quantitative lignin or tannin labeling procedure using a suitable P-31 containing probe, followed by the acquisition of a quantitative P-31 NMR spectrum in the presence of an internal standard. The high natural abundance of the P-31 nucleus allows for small amounts of the sample (similar to 30 mg) and short NMR acquisition times (similar to 30-120 min) with well-resolved P-31 signals that are highly dependent on the surrounding chemical environment of the labeled OH groups

Detection of velocity in high temperature liquid metals

Various efforts have been made to measure velocity in liquid metals. All of these efforts, however, share the same inherent limitation, namely, not being operative at the high temperatures required by liquid metals and liquid slags in an industrial application. In this paper, the current methods used were reviewed, and a new technique was presented for the measurement of velocity in high temperature liquid metals. In using this technique there are two stages. Starting with the calibration stage and then moving to the actual measurement stage by making use of the data obtained from calibration stage. Calibration proceeds in the following manner. Metallic spheres moving with a specific velocity are immersed in liquid metal held under isothermal conditions and at specific temperature. Their melting times are determined very accurately with a novel technique. These measurements are repeated for different metal bath temperatures and for different velocities of metallic spheres. In this manner it is possible to calculate the correlation between velocity and melting times for each metal bath temperature. During the actual measurement stage, when the metal bath temperature is known and its velocity is unknown, the magnitude of the unknown liquid metal velocity can be derived as follows: metallic spheres are immersed into the moving liquid metal and their melting times are determined. Using the above mentioned correlations, it will be shown that the magnitude of the unknown velocity in liquid metal can be deduced. This new technique was applied to high temperature liquid aluminum and liquid steel and these results were presented. The potential applicability of this technique in other liquid metals and liquid slags will also be discussed

An efficient and stereoselective dearylation of asarinin and sesamin tetrahydrofurofuran lignans to acuminatolide by methyltrioxorhenium/H2O2 and UHP systems

The synthesis of stereoisomers of acuminatolide is rare and requires complex and time-consuming multistep procedures. Asarinin (1) and sesamin (2), two diasteromeric tetrahydrofurofuran lignans, are efficiently mono-dearylated by methyltrioxorhenium (MTO, I) and hydrogen peroxide (H2O2) or urea hydrogen peroxide adduct (UHP) as primary oxidant to give (-)-(7R,8'R,8R)-acuminatolide (3A) and (+)-(7S,8R,8'R)-acuminatolide (3B), respectively, in high yield and diastereoselectivity (de > 98%). The oxidation of 1 was also performed with novel heterogeneous catalysts based on the heterogenation of MTO on poly(4-vinylpyridine) and polystyrene resins. In these latter cases 3A was obtained with a different yield and selectivity depending on the physical-chemical properties of the support. Cytotoxic effects of 3A and 3B in mammalian cell lines in vitro are also reported

A Theoretical Model of Underground Dipole Antennas for Communications in Internet of Underground Things

The realization of Internet of Underground Things (IOUT) relies on the establishment of reliable communication links, where the antenna becomes a major design component due to the significant impacts of soil. In this paper, a theoretical model is developed to capture the impacts of change of soil moisture on the return loss, resonant frequency, and bandwidth of a buried dipole antenna. Experiments are conducted in silty clay loam, sandy, and silt loam soil, to characterize the effects of soil, in an indoor testbed and field testbeds. It is shown that at subsurface burial depths (0.1-0.4m), change in soil moisture impacts communication by resulting in a shift in the resonant frequency of the antenna. Simulations are done to validate the theoretical and measured results. This model allows system engineers to predict the underground antenna resonance, and also helps to design an efficient communication system in IOUT. Accordingly, a wideband planar antenna is designed for an agricultural IOUT application. Empirical evaluations show that an antenna designed considering both the dispersion of soil and the reflection from the soil-air interface can improve communication distances by up to five times compared to antennas that are designed based on only the wavelength change in soil

Electrochemical characterization of organic coatings for protection of historic steel artefacts

Figuras en el archivo zipElectrochemical techniques are mainly known in the field of cultural heritage conservation as a tool for the elimination of corrosion layers or the removal of chlorides. However, these techniques are also a valuable tool for assessing the anti-corrosive efficiency of protective coatings. The aim of this study was to evaluate the performance of different coatings for their use in metallic heritage conservation using polarization resistance (Rp) and electrochemical impedance spectroscopy (EIS). Carbon steel samples were prepared to simulate the surface composition and morphology of historic steel artefacts, and coated by a conservator-restorer following the common practices in conservation treatments. Three commercial organic coatings have been studied: a microcrystalline wax (RenaissanceTM) and a methyl acrylate/ethyl methacrylate copolymer resin (ParaloidTM B-72) dissolved in acetone –both them commonly used in conservation and restoration treatments– and a ethylene copolymer wax emulsion in water (PoligenTM ES- 91009), that has not been used so far for this purposes. Four commercial corrosion inhibitor additives were added to the ParaloidTM B-72 resin and PoligenTM ES-91009 wax. The additives were commercial preparations with the following known active components: a blend of triazoles (M435), an ammonium salt of tricarboxylic acid (M370), a calcium sulphonate (M109), and a bis-oxazoline (Alkaterge-TTM). Rp and EIS results showed that the best protection of the steel specimens was afforded by PoligenTM ES-91009 when applied in thick layers. None of the additives have shown a clear improvement of the protection properties of the coatings, and one of them impaired the barrier effect of the coating.Acknowledgements The authors express their gratitude to the Sixth Framework Programme of the European Commission for financial support of PROMET Project (Contract 509126). D.M. Bastidas expresses his gratitude to the CSIC of Spain for his contract under the I3P Programme, co-financed by the European Social Fund.Peer reviewe

Dependence of e-cloud on the longitudinal bunch profile: studies in the PS & extension to the HL-LHC

Recent studies have shown that the prospects for significantly increasing bunch intensities in the LHC for the luminosity upgrade (HL-LHC) may be severely limited by the available cryogenic cooling capacity and the electron-cloud (EC) driven beam instability. However, it is planned that during the HL-LHC era the bunch intensities in the LHC will go up by nearly a factor of two compared to the LHC-design values. This motivates the exploration of additional EC mitigation techniques that can be adopted in addition to those already in place. Preliminary simulations indicated that long flat bunches can be beneficial over Gaussian bunches to reduce the EC build up. Rigorous studies using realistic bunch profiles have never been done. Therefore, we have undertaken an in-depth investigation in the CERN 26 GeV PS to see if we can validate the previous findings and, in particular, if flattening the bunch can mitigate the EC. Here we present the results from dedicated EC measurements in the PS using a variety of bunch shapes and a comparison with simulations. Finally, we investigate if reshaping the bunch profiles using a 2nd harmonic rf cavity can mitigate EC in the HL-LHC

Nonlinear waves in hyperbolic metamaterials: focus on solitons and rogues

The investigation of hyperbolic metamaterials, shows that metal layers that are part of graphene structures, and also types I and II layered systems, are readily controlled. Since graphene is a nicely conducting sheet it can be easily managed. The literature only eveals a, limited, systematic, approach to the onset of nonlinearity, especially for the methodology based around the famous nonlinear Schrödinger equation [NLSE]. This presentation reveals nonlinear outcomes involving solitons sustained by the popular, and more straightforward to fabricate, type II hyperbolic metamaterials. The NLSE for type II metatamaterials is developed and nonlinear, non-stationary diffraction and dispersion in such important, and active, planar hyperbolic metamaterials is developed. For rogue waves in metamaterials only a few recent numerical studies exist. The basic model assumes a uniform background to which is added a time-evolving perturbation in order to witness the growth of nonlinear waves out of nowhere. This is discussed here using a new NLSE appropriate to hyperbolic metamaterials that would normally produce temporal solitons. The main conclusion is that new pathways for rogue waves can emerge in the form of Peregrine solitons (and near-Peregrines) within a nonlinear hyperbolic metamaterial, based upon double negative guidelines, and where, potentially, magnetooptic control could be practically exerted